Mercury to Gold
Posted: Sat May 07, 2011 4:01 pm
From 2006 or earlier wikipedia article:
The artificial production of gold is the age-old dream of the alchemists. It is possible in particle accelerators or nuclear reactors, although the production cost is currently many times the market price of gold. Since there is only one stable gold isotope, 197Au, nuclear reactions must create this isotope in order to produce usable gold.
Gold obtained by mining has copper and silver impurities. Gold of higher purity can be made through the photoneutron process:[citation needed]
Mercury 198 + 6.8MeV gamma ray --) 1 neutron + Mercury 197 (half-life 2.7 days --) Gold 197 + 1 positron)
These energy levels allow a more efficient neutron source than the Spallation Neutron Source.
Gold synthesis in an accelerator
Gold synthesis in a particle accelerator is possible in many ways. The Spallation Neutron Source has a liquid mercury target that will be transmuted into gold, platinum, and iridium, which are lower in atomic number.
Gold synthesis in a nuclear reactor
Gold was first synthesized from mercury by neutron bombardment in 1941, but the isotopes of gold produced were all radioactive.
Gold can currently be manufactured in a nuclear reactor by irradiation either of platinum or mercury. Since platinum is more expensive than gold, platinum is economically unsuitable as a raw material.
Only the mercury isotope 196Hg, which occurs with a frequency of 0.15% in natural mercury, can be converted to gold by neutron capture, and following electron capture-decay into 197Au with slow neutrons. Other mercury isotopes are converted when irradiated with slow neutrons into one another or formed mercury isotopes, which beta decay into thallium.
Using fast neutrons, the mercury isotope 198Hg, which composes 9.97% of natural mercury, can be converted by splitting off a neutron and becoming 197Hg, which then disintegrates to stable gold. This reaction, however, possesses a smaller activation cross-section and is feasible only with un-moderated reactors.
It is also possible to eject several neutrons with very high energy into the other mercury isotopes in order to form 197Hg. However such high-energy neutrons can be produced only by particle accelerators[clarification needed].
http://en.wikipedia.org/wiki/Synthesis_ ... om_Mercury
-------------------------------------------------
For the synthesis eqn:
Mercury 198 + 6.8MeV gamma ray --) 1 neutron + Mercury 197 (half-life 2.7 days --) Gold 197 + 1 positron)
Since
"Gamma rays from radioactive decay commonly have energies of a few hundred keV, and almost always less than 10 MeV"
http://en.wikipedia.org/wiki/Gamma_ray
So does that mean there could be elements with radioactive decay of ~ 7 MeV gamma that could turn mercury into gold cheaply in a reasonable time frame and then separate other isotopes of mercury out that can't convert to gold by using something like this:
http://www.physorg.com/news159098428.html
or this:
http://en.wikipedia.org/wiki/Chemica...sport_reaction
Mercury is rare in the earth's crust but a lot comes up as a byproduct of deep oil drilling.
The artificial production of gold is the age-old dream of the alchemists. It is possible in particle accelerators or nuclear reactors, although the production cost is currently many times the market price of gold. Since there is only one stable gold isotope, 197Au, nuclear reactions must create this isotope in order to produce usable gold.
Gold obtained by mining has copper and silver impurities. Gold of higher purity can be made through the photoneutron process:[citation needed]
Mercury 198 + 6.8MeV gamma ray --) 1 neutron + Mercury 197 (half-life 2.7 days --) Gold 197 + 1 positron)
These energy levels allow a more efficient neutron source than the Spallation Neutron Source.
Gold synthesis in an accelerator
Gold synthesis in a particle accelerator is possible in many ways. The Spallation Neutron Source has a liquid mercury target that will be transmuted into gold, platinum, and iridium, which are lower in atomic number.
Gold synthesis in a nuclear reactor
Gold was first synthesized from mercury by neutron bombardment in 1941, but the isotopes of gold produced were all radioactive.
Gold can currently be manufactured in a nuclear reactor by irradiation either of platinum or mercury. Since platinum is more expensive than gold, platinum is economically unsuitable as a raw material.
Only the mercury isotope 196Hg, which occurs with a frequency of 0.15% in natural mercury, can be converted to gold by neutron capture, and following electron capture-decay into 197Au with slow neutrons. Other mercury isotopes are converted when irradiated with slow neutrons into one another or formed mercury isotopes, which beta decay into thallium.
Using fast neutrons, the mercury isotope 198Hg, which composes 9.97% of natural mercury, can be converted by splitting off a neutron and becoming 197Hg, which then disintegrates to stable gold. This reaction, however, possesses a smaller activation cross-section and is feasible only with un-moderated reactors.
It is also possible to eject several neutrons with very high energy into the other mercury isotopes in order to form 197Hg. However such high-energy neutrons can be produced only by particle accelerators[clarification needed].
http://en.wikipedia.org/wiki/Synthesis_ ... om_Mercury
-------------------------------------------------
For the synthesis eqn:
Mercury 198 + 6.8MeV gamma ray --) 1 neutron + Mercury 197 (half-life 2.7 days --) Gold 197 + 1 positron)
Since
"Gamma rays from radioactive decay commonly have energies of a few hundred keV, and almost always less than 10 MeV"
http://en.wikipedia.org/wiki/Gamma_ray
So does that mean there could be elements with radioactive decay of ~ 7 MeV gamma that could turn mercury into gold cheaply in a reasonable time frame and then separate other isotopes of mercury out that can't convert to gold by using something like this:
http://www.physorg.com/news159098428.html
or this:
http://en.wikipedia.org/wiki/Chemica...sport_reaction
Mercury is rare in the earth's crust but a lot comes up as a byproduct of deep oil drilling.